Degasser PRE-V (page 1 of 3)
Oxygen solubility in water
Air can be dissolved in water without any visible airbubbles. Occurrence
of visible bubbles may indicate that the temperature
and the pressure are such that the saturation point
bas been reached. lf not, the air-bubbles will disappear.
However, air-bubbles may appear anywhere in the plant.
In e.g. local vacuum zones, restrictions, pumps etc,
and aggregate in parts where it is calm, in e.g. batteries
and heat exchangers. A degassing issue will appear.
The solubility of oxygen in water is defined by the
air-pressure and by the water temperature. The phenomenon
is described by Henry's Law. Air is mainly composed
of oxygen and nitrogen in fixed proportions. Oxidation
processes in the plant will in the long run cause damage
to the installed equipment. In order to prevent this,
the presence of oxygen must be eliminated to the extent
possible. One possible solution is to degas the water
in the system and significantly reduce the quantity
of air/oxygen. |

3-step degasser
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In PREMA's degasser this is accomplished in three
steps.
A continunus flow of water is led through the PRE-V
equipment. In which the water is degassed in a 3-step
process of successive pressure reductions. This process
affects neither the pressure nor the flow in the main
system. Drainage and emptying can be accomplished
without interruption of the main system operation.
The pump and the automatic valves in the equipment
cooperate for an optimal degassing effect irrespective
of the main system pressure and flow variations.
STEP 1
The targeted pressure level is dependent on the current
system pressure. The pressure reduction is made in
a way that keeps the flow constant if the system pressure
is lower than 1.0 bar the pressure reduction is insufficient
and the degassing effect wili fail to appear. For
successful degassing in step 1, the system pressure
must exceed 1.0 bar. Another important function of
step 1 is to protect the pump from accumulations of
air and thus prevent a possibie breakdown.
STEP 2
The purpose is to estabiish a negative pressure by further
reducing the pressure from the level established in
step 1. The dissolved gas will not be released in this
step due to the negative pressure. The air-bubbles will
consequently follow the water flow into the pump.
STEP 3
In step 3 the pressure is reduced even further from
the level established in step 2. The degassing effect
is strong since a big partial negative pressure is obtained
in the pump blading. The air-bubbles are not dissolved
into the water immediateiy because of the hysteresis
effect. Consequently there will be enough time to separate
and blow off the gas that is set free.
The degassing process
During the degassing process, small bubbles of air are
set free. These bubbles consist, among other things,
of oxygen. The bubbles are caught in a net in the collecting
vessel, in which it is calm. The accumulated air is
blown off by means of a conventional degasser (equipped
with non-return valves). This process reduces the saturation
ratio for the water and thus ellminates accumulation
of air in heat exchangers, batteries, radiators, baffles
etc.
Magnetite
Removal of oxygen from the system water also prevents
the formation of magnetite. Magnetite is a black oxide
of iron, which is formed when the material in pipes
and fittings corrode. The magnetite colors the water
almost completely black. Pump wheels, garniture of fittings
and parts of iron erode when magnetite precipitates
in the system water. The result is requirements for
major repairs and thus high costs. Plants in which black
system water bas been observed is at risk. A continuous
process of formation of magnetite is active and batteries
and heat exchangers have already started to deteriorate.
It is important to immediately call for professional
cleaning of the system in order to eliminate oxygen
and to slow down the oxidation process. It is advsable
to equip also new installations with a degasser in order
to prevent corrosion, break down and expensive replacement
of equipment. Thls ensures big cost savings and prevents
interruption of operation due to formation of magnetite.
Magnetite might have a flaky structure, especialiy in
the presence of calcareous water. The flakes might get
stuck in heat exchangers, batteries etc and can only
be removed by using strong solvents. If the result from
cleaning is not successful, the apparatus must be replaced.
It is much easier to handle free magnetite, since it
can be removed by using magnetic devices. Strong acidification
of the system water takes place during the process of
formation of magnetite. The acidification accelerates
the oxidation process. Therefore it is generally advisable
to renew the system water when a degasser is installed.
In "cold" systems the freeze protection deteriorates
as glycol is consumed. During this process there is
a risk of growth of aerobe bacteria. |
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